Title of article
Computational evaluation of asymmetric Diels–Alder reactions of vinylboranes with chiral dienes
Author/Authors
Silvina C. Pellegrinet، نويسنده , , Silvina C. and Silva، نويسنده , , Marيa A. and Goodman، نويسنده , , Jonathan M.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
4
From page
2461
To page
2464
Abstract
The asymmetric Diels–Alder reactions of dichlorovinylborane and vinyl-9-BBN with two chiral dienes have been studied theoretically. Calculations suggest high reactivity and regio- and stereoselectivity could be achieved in these processes giving the anti para endo product. This class of reactions represents a potential stereoselective approach to a variety of chiral carbocycles.
Keywords
DFT study , Asymmetric Diels–Alder reactions , Vinylboranes
Journal title
Tetrahedron Letters
Serial Year
2005
Journal title
Tetrahedron Letters
Record number
1845296
Link To Document