Author/Authors :
Singh، نويسنده , , Chandan and Srivastav، نويسنده , , Naveen Chandra and Srivastava، نويسنده , , Nisha and Puri، نويسنده , , Sunil K.، نويسنده ,
Abstract :
Cyclopropyl carbinols 1a–e react with H2O2 in the presence of concd H2SO4 at 0–5 °C to furnish the corresponding hydroperoxides 2a–e in 45–82% yields. This efficient trapping of cyclopropylmethyl cations by the hydroperoxy group has been exploited to prepare compounds 14–23, a new series of cyclopropyl substituted β-peroxy-lactones.
