Title of article
The fragmentation of exo-5-norbornenyl-2-oxychlorocarbene: stereochemistry and mechanism
Author/Authors
Fu، نويسنده , , Xiaolin and Moss، نويسنده , , Robert A. and Sauers، نويسنده , , Ronald R. and Wipf، نويسنده , , Peter، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
4
From page
4265
To page
4268
Abstract
The fragmentation of (S)-exo-5-norbornenyl-2-oxychlorocarbene (3) affords (S)-exo-5-norbornenyl-2-chloride (4), (R)-endo-5-norbornenyl-2-chloride (5), and (S)-3-nortricyclyl chloride (6) with varying degrees of enantiomeric excess. A weighted blend of SNi fragmentation and escape to norbornenyl/nortricyclyl ion pairs rationalizes the stereochemical results.
Journal title
Tetrahedron Letters
Serial Year
2005
Journal title
Tetrahedron Letters
Record number
1845955
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