The direct synthesis of tertiary amines with three different substituents via the reaction of primary amines, alkyl halides, and α-chlorine substituted allylsilanes catalyzed by Lewis acids

Tertiary amines with three different substituents were obtained in a single step by the CuCl/B(OMe)3 or B(OMe)3-catalyzed reaction of α-chlorine substituted allylsilanes, alkyl halides, and primary amines.