Title of article
The synthesis and catalytic application of spacer-modified diol-functionalised Merrifield resins
Author/Authors
Dyer، نويسنده , , Philip W. and Handa، نويسنده , , Sandeep and Reeve، نويسنده , , Toby B. and Suhard، نويسنده , , Samuel، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
4
From page
4753
To page
4756
Abstract
A range of alkyl spacer-tethered 1,2- and 1,3-diols have been prepared from commercially available Merrifield resin (1) and (4-chloromethyl)phenylpentyl-polystyrene-co-divinylbenzene (2). The utility of these resin-bound diols as supports for the Ti(IV)-catalysed Diels–Alder reaction has been exemplified and it has been demonstrated that the length of the tether has a direct effect upon the catalytic activity.
Keywords
Polymer-supported , Catalysis , Lewis acid , Diels–Alder , Merrifield resin
Journal title
Tetrahedron Letters
Serial Year
2005
Journal title
Tetrahedron Letters
Record number
1846121
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