Title of article
Kinetic resolution of racemic epoxides using a chiral diamine catalyst
Author/Authors
Gayet، نويسنده , , Arnaud and Andersson، نويسنده , , Pher G. Andersson، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
3
From page
4805
To page
4807
Abstract
The kinetic resolution of a variety of racemic epoxides has been performed using a chiral bicyclic diamine ligand. Using 5 mol % of catalyst very high selectivity could be achieved; both epoxide and the corresponding allylic alcohol could be obtained in up to 99% ee.
Keywords
kinetic resolution , Allylic alcohol , Epoxide rearrangement , Chiral diamine
Journal title
Tetrahedron Letters
Serial Year
2005
Journal title
Tetrahedron Letters
Record number
1846140
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