Title of article
Pentamethylcyclopentadienide in organic synthesis: nucleophilic addition of lithium pentamethylcyclopentadienide to aromatic aldehydes and carbon–carbon bond cleavage of the adducts affording the parent aldehydes
Author/Authors
Yagi، نويسنده , , Kazunari and Yorimitsu، نويسنده , , Hideki and Oshima، نويسنده , , Koichiro، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
3
From page
4831
To page
4833
Abstract
Treatment of aromatic aldehyde with lithium pentamethylcyclopentadienide provided the corresponding carbinol in excellent yield. The carbinol returns to the parent aldehyde and pentamethylcyclopentadiene upon exposure to an acid or due to heating. The combination of the two reactions can represent a protection of aromatic aldehyde.
Keywords
PROTECTION , Aldehydes , Pentamethylcyclopentadiene , nucleophilic addition , carbon–carbon bond cleavage
Journal title
Tetrahedron Letters
Serial Year
2005
Journal title
Tetrahedron Letters
Record number
1846150
Link To Document