Title of article
Anodic oxidation of chiral sulfinylamines: a new route to highly diastereoselective α-alkylation of piperidine
Author/Authors
Serge Turcaud، نويسنده , , Serge and Martens، نويسنده , , Thierry and Sierecki، نويسنده , , Emma and Pérard-Viret، نويسنده , , Joëlle and Royer، نويسنده , , Jacques، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
4
From page
5131
To page
5134
Abstract
The anodic oxidation of some chiral non-racemic N-arylsulfinyl piperidines was investigated and for the first time α methoxylated sulfinyl piperidines were obtained. The so-formed compounds are equivalent of chiral N-sulfinyliminiums and used as new intermediates for the preparation of chiral α-substituted piperidine derivatives in good yield and diastereoselectivity.
Keywords
Pelletierine , Anodic oxidation , Diastereoselective alkylation , Sulfinylamine
Journal title
Tetrahedron Letters
Serial Year
2005
Journal title
Tetrahedron Letters
Record number
1846252
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