Title of article :
A new type of anomalous ozonolysis in strained allylic bicycloalkan-1-ols
Author/Authors :
Garcيa Martيnez، نويسنده , , Antonio and Teso Vilar، نويسنده , , Enrique and Garcيa Fraile، نويسنده , , Amelia and de la Moya Cerero، نويسنده , , Santiago and Lora Maroto، نويسنده , , Beatriz، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2005
Abstract :
7,7-Dimethyl-2-methylenenorbornan-1-ol, a fenchone-derived strained allylic bicycloalkan-1-ol, undergoes an unexpected new type of anomalous ozonolysis to yield a mixture of a rearranged β-hydroxyketone and a fragmented carboxylic acid. The proposed mechanisms involves two unusual different trappings for two different key Criegee’s intermediates.
Keywords :
Cleavage reactions , Ozonolysis , Bicycles , substituent effects
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
