Title of article
A new type of anomalous ozonolysis in strained allylic bicycloalkan-1-ols
Author/Authors
Garcيa Martيnez، نويسنده , , Antonio and Teso Vilar، نويسنده , , Enrique and Garcيa Fraile، نويسنده , , Amelia and de la Moya Cerero، نويسنده , , Santiago and Lora Maroto، نويسنده , , Beatriz، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
3
From page
5157
To page
5159
Abstract
7,7-Dimethyl-2-methylenenorbornan-1-ol, a fenchone-derived strained allylic bicycloalkan-1-ol, undergoes an unexpected new type of anomalous ozonolysis to yield a mixture of a rearranged β-hydroxyketone and a fragmented carboxylic acid. The proposed mechanisms involves two unusual different trappings for two different key Criegee’s intermediates.
Keywords
Cleavage reactions , Ozonolysis , Bicycles , substituent effects
Journal title
Tetrahedron Letters
Serial Year
2005
Journal title
Tetrahedron Letters
Record number
1846261
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