Title of article
Novel synthesis of α-nitroalkenes from nitroalkanes via halogenation of intermediate N,N-bis(silyloxy)enamines
Author/Authors
Kunetsky، نويسنده , , Roman A. and Dilman، نويسنده , , Alexander D. and Struchkova، نويسنده , , Marina I. and Tartakovsky، نويسنده , , Vladimir A. and Ioffe، نويسنده , , Sema L. Ioffe، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
3
From page
5203
To page
5205
Abstract
An approach to conjugated nitroalkenes via oxidation of N,N-bis(silyloxy)enamines with bromine or iodine in the presence of tetra-n-butylammonium acetate is described. The acetate ion plays a key role by acting as a mild desilylating reagent. This new strategy allows the synthesis of α-nitroalkenes from the corresponding nitroalkanes.
Keywords
Nitroalkenes , Halogenation , N , Silyl nitronates , N-bis(silyloxy)enamines
Journal title
Tetrahedron Letters
Serial Year
2005
Journal title
Tetrahedron Letters
Record number
1846279
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