Title of article :
Pd-catalyzed couplings of (α-fluoro)vinyl tris(trimethylsilyl)germanes
Author/Authors :
Wang، نويسنده , , Zhizhong and Gonzalez، نويسنده , , Aurelio and Wnuk، نويسنده , , Stanislaw F.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2005
Abstract :
The (α-fluoro)vinyl tris(trimethylsilyl)germanes undergo Pd-catalyzed cross-couplings with aryl and alkenyl halides upon oxidative treatment with hydrogen peroxide under basic aqueous conditions to give access to fluoroalkenes and fluorodienes with retention of stereochemistry.
Keywords :
Organogermanes , Cross-coupling reactions , Fluoroalkenes , Fluorodienes
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters