Title of article :
First enantiospecific synthesis of marine nor-sesquiterpene (+)-austrodoral from (−)-sclareol
Author/Authors :
Alvarez-Manzaneda، نويسنده , , E.J. and Chahboun، نويسنده , , Agustيn R. and Barranco، نويسنده , , I. and Cabrera Torres، نويسنده , , E. and Alvarez، نويسنده , , E. and Alvarez-Manzaneda، نويسنده , , R.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2005
Abstract :
A short and efficient synthesis of the rearranged nor-sesquiterpenes (+)-austrodoral (1) and (+)-austrodoric acid (2), recently isolated from the Antarctic marine mollusk Austrodoris kerguelenensis, from diterpene (−)-sclareol (4) is reported. The key step of the sequence is the pinacol rearrangement of the drimanetriol 11.
Keywords :
Terpenes , Marine metabolites , iodine , enantiospecific synthesis , Pinacol rearrangement , Triphenylphosphine
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
