Title of article :
BINOL-derived N-phosphino sulfoximines as ligands for asymmetric catalysis
Author/Authors :
Reetz، نويسنده , , Manfred T. and Bondarev، نويسنده , , Oleg G. and Gais، نويسنده , , Hans-Joachim and Bolm، نويسنده , , Carsten، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2005
Abstract :
BINOL-derived N-phosphino sulfoximines have been prepared for the first time and tested as ligands in asymmetric transition metal catalysis. Up to 99% ee was achieved in the Rh-catalyzed asymmetric hydrogenation of functionalized olefins and up to 66% ee in the Pd-catalyzed allylic alkylation.
Keywords :
Hydrogenation , allylation , Asymmetric reactions , N-Phosphino sulfoximines , Rhodium
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
