A facile S-transalkylation of 2,2′-bipyridine alkyl sulfides—a new tool for the synthesis of annulated biheterocycles

A simple and efficient synthesis of annulated 2,2′-bipyridinium salts with attached dihydrothiazole or dihydro-1,3-thiazine rings has been developed through tandem S-transalkylation/intramolecular ring closure of 2,2′-bipyridine alkyl sulfides. The structures were confirmed by X-ray crystallographic analysis.