Title of article :
Synthesis of highly substituted pyrrolidines via palladium catalysed formal [2+3] cycloaddition of 5-vinyloxazolidin-2-ones to activated alkenes
Author/Authors :
Knight، نويسنده , , Julian G. and Tchabanenko، نويسنده , , Kirill and Stoker، نويسنده , , Paul A. and Harwood، نويسنده , , Simon J.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2005
Abstract :
Glycine-derived N-tosyl-5,5-divinyloxazolidin-2-one 10 undergoes a palladium catalysed decarboxylative ring-opening cyclization with strongly electron deficient alkylidenemalonate derivatives to give highly substituted pyrrolidines 14 containing two contiguous quaternary centres.
Keywords :
Catalytic , cycloaddition , pyrrolidine , Synthesis , PALLADIUM
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
