Title of article :
Stereoselective electrocatalytic transformation of arylidene- or alkylidenemalononitriles and malonate into alkyl (1R,5R,6R)* 6-substituted 5-cyano-4,4-dialkoxy-2-oxo-3-azabicyclo[3.1.0]hexane-1-carboxylates
Author/Authors :
Elinson، نويسنده , , Michail N. and Feducovich، نويسنده , , Sergey K. and Starikova، نويسنده , , Zoya A. and Vereshchagin، نويسنده , , Anatolii N. and Gorbunov، نويسنده , , Sergey V. and Nikishin، نويسنده , , Gennady I.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2005
Abstract :
Electrolysis of arylidene- or alkylidenemalononitriles and malonate in alcohol in an undivided cell in the presence of sodium halide as mediator results in the stereoselective formation of alkyl (1R,5R,6R)* 6-substituted 5-cyano-4,4-dialkoxy-2-oxo-3-azabicyclo[3.1.0]hexan-1-carboxylates in 50–70% yields.
Keywords :
Electrocatalytic transformation , Mediators , Malonate , Arylidenemalononitriles , Bicyclic pyrrolidones , electrolysis , stereoselectivity
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
