Title of article
Formation of 1-methylene-2-vinylcyclopropane by intramolecular -cycloalkylation reaction
Author/Authors
Brandau، نويسنده , , Sven and Frِhlich، نويسنده , , Roland and Hoppe، نويسنده , , Dieter، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
3
From page
6709
To page
6711
Abstract
The synthesis of a substituted (Z)-2-(2-methylenecyclopropyl)vinyl N,N-dialkylcarbamate is presented. Via α-deprotonation of a 4-chloromethyl-2,4-dienyl carbamate and succeeding intramolecular S E ′ -cycloalkylation reaction, the diastereomerically pure cyclopropane is formed.
Keywords
Cyclopropanes , Cycloalkylation , Carbamates
Journal title
Tetrahedron Letters
Serial Year
2005
Journal title
Tetrahedron Letters
Record number
1846743
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