Title of article :
Conformational control of flexible molecular tweezers by intramolecular CH/π interaction
Author/Authors :
Iwamoto، نويسنده , , Hajime and Takahashi، نويسنده , , Nobuaki and Maeda، نويسنده , , Takuma and Hidaka، نويسنده , , Yusuke and Fukazawa، نويسنده , , Yoshimasa، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2005
Abstract :
The synthesis of new flexible molecular tweezers based on 3,4,8,10,11,13-hexahydro-1H,6H-2,5,9,12-tetraoxa-benzo[1,2:4,5]dicyclooctene bearing two naphthalenes is presented. Intramolecular CH/π interaction between the alkyl ring and the two terminal naphthalenes controls the conformation to give a self-quenched cleft form.
Keywords :
molecular tweezers , conformational control , CH/? Interaction
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters