Title of article
A highly enantioselective catalyst for asymmetric hydroformylation of [2.2.1]-bicyclic olefins
Author/Authors
Huang، نويسنده , , Jinkun and Bunel، نويسنده , , Emilio and Allgeier، نويسنده , , Alan and Tedrow، نويسنده , , Jason and Storz، نويسنده , , Thomas A Preston، نويسنده , , J. and Correll، نويسنده , , Tiffany and Manley، نويسنده , , Deana and Soukup، نويسنده , , Troy and Jensen، نويسنده , , Randy and Syed، نويسنده , , Rashid and Moniz، نويسنده , , George and Larsen، نويسنده , , Robert and Martinelli، نويسنده , , Michael ، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
4
From page
7831
To page
7834
Abstract
Rh(CO)2(acac)/TangPhos was found to be a highly enantioselective catalyst for asymmetric hydroformylation of norbornylene under mild conditions. Application of the protocol to the desymmetrization of other [2.2.1]-bicyclic olefins gave moderate to excellent enantioselectivity (55–92% ee).
Keywords
Asymmetric hydroformylation , TangPhos
Journal title
Tetrahedron Letters
Serial Year
2005
Journal title
Tetrahedron Letters
Record number
1847266
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