Title of article
Towards schizozygine: synthesis of 15α-hydroxystrempeliopine
Author/Authors
Pilar??k، نويسنده , , Tom?? and Havl??ek، نويسنده , , Jaroslav and H?j??ek، نويسنده , , Josef، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
3
From page
7909
To page
7911
Abstract
15α-Hydroxystrempeliopine (6), a model hexacyclic base for our planned total synthesis of schizozygine (2), has been synthesized using a Zn-mediated reductive rearrangement of indolenine 14 as the key step. The structure and relative stereochemistry of 6 were assigned by a combination of COSY, NOESY, HSQC and HMBC correlations.
Keywords
Indole alkaloids , Strempeliopine , Schizozygane alkaloids , Alkaloid synthesis , Reductive rearrangement , Indolenine
Journal title
Tetrahedron Letters
Serial Year
2005
Journal title
Tetrahedron Letters
Record number
1847323
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