Title of article :
Synthesis of 3,5-dioxoalkanoates, 3,5-dioxopimelates and 2,4-dioxoadipates by acylation of 1,3-bis-silyl enol ethers
Author/Authors :
Reim، نويسنده , , Stefanie and Nguyen، نويسنده , , Van Thi Hong and Albrecht، نويسنده , , Uwe and Langer، نويسنده , , Peter، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2005
Abstract :
3,5-Dioxoalkanoates, 3,5-dioxopimelates and 2,4-dioxoadipates were prepared by acylation of 1,3-bis-silyl enol ethers with carboxylic chlorides, methyl 3-chloro-3-oxopropanoate and ethyl 2-chloro-2-oxoacetate, respectively.
Keywords :
Acid Chlorides , acylation , polyketides , Silyl enol ethers , regioselectivity
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters