Title of article :
On the nucleophilic tele-substitution of dichloropyrazines by metallated dithianes
Author/Authors :
Torr، نويسنده , , Jane E. and Large، نويسنده , , Jonathan M. and Horton، نويسنده , , Peter N. and Hursthouse، نويسنده , , Michael B. and McDonald، نويسنده , , Edward، نويسنده ,
Issue Information :
دوماهنامه با شماره پیاپی سال 2006
Pages :
4
From page :
31
To page :
34
Abstract :
The reaction of dichloropyrazines with a dithiane anion gave isomers of the expected formylated chloropyrazines after deprotection with methyl iodide. A tele-substitution mechanism accounts for these observations and is supported by deuterium labelling studies.
Keywords :
Tele-substitution , Pyrazines , metallation , dithianes
Journal title :
Tetrahedron Letters
Serial Year :
2006
Journal title :
Tetrahedron Letters
Record number :
1847957
Link To Document :
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