Title of article
Stereoselective conjugate addition of nitrogen nucleophiles to 3,3,3-trifluoro-1-nitropropene
Author/Authors
Turconi، نويسنده , , Joël and Lebeau، نويسنده , , Luc and Paris، نويسنده , , Jean-Marc and Mioskowski، نويسنده , , Charles، نويسنده ,
Issue Information
دوماهنامه با شماره پیاپی سال 2006
Pages
3
From page
121
To page
123
Abstract
In order to access 1,2-diamines incorporating perfluorinated groups, the Michael-like addition of nitrogen nucleophiles to 3,3,3-trifluoro-1-nitropropene has been investigated using racemic and optically pure nucleophiles such as amines, amides, oxazolidin(on)es, and thiazolidin(on)es. Complete diastereoselectivity of the addition was achieved with 4-phenylthiazolidine-2-thione.
Keywords
Diastereoselective aza-Michael addition , 3 , 3 , 3-Trifluoro-1-nitropropene , Oxazolidinethione , Oxazolidinone , Perfluoroalkyl nitroalkene
Journal title
Tetrahedron Letters
Serial Year
2006
Journal title
Tetrahedron Letters
Record number
1847995
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