Title of article
Stereospecific rearrangement of α-hydroxyepoxide: efficient approach to the trans-bicyclo[9.3.0]tetradecane core en route to clavulactone
Author/Authors
Sun، نويسنده , , Bingfeng and Xu، نويسنده , , Xingxiang، نويسنده ,
Issue Information
دوماهنامه با شماره پیاپی سال 2006
Pages
4
From page
299
To page
302
Abstract
We document a synthetic route to trans-bicyclo[9.3.0]tetradecanes. The strategy is based on a quantitative and stereospecific Lewis acid mediated rearrangement of α-hydroxyepoxide to β-hydroxyketone, which paved the way for the synthesis of clavulactone and clavirolides.
Journal title
Tetrahedron Letters
Serial Year
2006
Journal title
Tetrahedron Letters
Record number
1848266
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