Title of article
Enantioselective synthesis of the bicyclo[4.3.0]nonane ring system of the pinguisane-type sesquiterpenoids via a Brّnsted acid promoted transannular enol alkylation
Author/Authors
Clarke، نويسنده , , Paul A. and Black، نويسنده , , Richard J.G. and Blake، نويسنده , , Alexander J.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2006
Pages
3
From page
1453
To page
1455
Abstract
The bicyclo[4.3.0]nonane ring system of the pinguisane-type sesquiterpenoid natural products, including the vicinal quaternary stereocentres, has been synthesised as a single enantiomer via a novel Brّnsted acid promoted transannular alkylation of an enol with an unactivated alkene.
Keywords
Vicinal quaternary centres , Pinguisane sesquiterpenoids , Enol alkylation , Transannular cyclisations , Brّnsted acid
Journal title
Tetrahedron Letters
Serial Year
2006
Journal title
Tetrahedron Letters
Record number
1849020
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