Title of article :
Organosulfur oxidation by hydrogen peroxide using a dinuclear Mn-1,4,7-trimethyl-1,4,7-triazacyclononane complex
Author/Authors :
Smith، نويسنده , , John R. Lindsay and Murray، نويسنده , , Jane M.Walton ·
Jennifer L. Allen، نويسنده , , Paul H. and Lowdon، نويسنده , , Terry R.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2006
Abstract :
A mechanistic study of organosulfide oxidation by H2O2, using a dinuclear manganese complex as the catalyst, has revealed an unusual switch in the philicity of the oxidant for the first and the second oxygen transfer steps; this switch has been exploited to tune selectivity for each of the products.
Keywords :
Oxidation , Sulfide , Sulfoxide , Catalysis , Manganese 1 , 7-trimethyl-1 , 4 , 4 , 7-triazacyclononane complexes , Hydrogen peroxide
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
