Title of article
Unprecedented two-step synthesis of symmetrical diarylamines from 2-alkyl-1,3-dinitropropanes
Author/Authors
Ballini، نويسنده , , Roberto and Barboni، نويسنده , , Luciano and Femoni، نويسنده , , Cristina and Giarlo، نويسنده , , Guido and Palmieri، نويسنده , , Alessandro، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2006
Pages
3
From page
2295
To page
2297
Abstract
This letter reports a new, two-step synthesis of symmetrical diarylamines from 1,3-dinitropropanes, by their reaction with acrolein under basic conditions (Al2O3, neat), followed by aromatisation of the obtained 2,4-dinitrocyclohexanols, through their treatment with four equivalents of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU), in acetonitrile as a solvent, and warming overnight at 60 °C.
Keywords
1 , Diarylamines , aromatization , 3-Dinitropropanes , one-pot synthesis
Journal title
Tetrahedron Letters
Serial Year
2006
Journal title
Tetrahedron Letters
Record number
1849399
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