Title of article :
The use of an ionic liquid in asymmetric catalytic allylic amination
Author/Authors :
Lyubimov، نويسنده , , Sergey E. and Davankov، نويسنده , , Vadim A. and Gavrilov، نويسنده , , Konstantin N.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2006
Abstract :
Asymmetric amination of 1,3-diphenyl-2-propenyl acetate with di-n-propylamine catalysed by palladium/P∗-chiral diamidophosphites was carried out in [ bdmim ] BF 4 - ionic liquid, THF and CH2Cl2 with up to 90% ee. The catalyst can be reused three times without loss in enantioselectivity.
Keywords :
Ionic liquid , Asymmetric Pd-catalysed amination , P-monodentate phosphite ligands
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
