Title of article
Reaction of [60]fullerene with CF3COOHal affords an unusual 1,3-dioxolano-[60]fullerene
Author/Authors
Troshin، نويسنده , , Pavel A. and Peregudov، نويسنده , , Alexander S. and Lyubovskaya، نويسنده , , Rimma N.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2006
Pages
4
From page
2969
To page
2972
Abstract
Reaction of C60 with acyl hypohalogenites CF3COOBr or CF3COOI in the presence of water affords an orthoester-type 1,3-dioxolanofullerene in 40–50% yield. This method cannot be applied for the synthesis of 1,3-dioxolanofullerenes bearing aryl- or alkyl-groups since they undergo non-selective halogenation under the reaction conditions.
Keywords
radical addition , C60 , Fullerenes
Journal title
Tetrahedron Letters
Serial Year
2006
Journal title
Tetrahedron Letters
Record number
1849791
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