Title of article
Noncovalent paramagnetic complexes: detection of halogen bonding in solution by ESR spectroscopy
Author/Authors
Mugnaini، نويسنده , , Veronica and Punta، نويسنده , , Carlo and Liantonio، نويسنده , , Rosalba and Metrangolo، نويسنده , , Pierangelo and Recupero، نويسنده , , Francesco and Resnati، نويسنده , , Giuseppe and Pedulli، نويسنده , , Gian Franco and Lucarini، نويسنده , , Marco، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2006
Pages
5
From page
3265
To page
3269
Abstract
Halogen-bonded complexes between aliphatic and aromatic iodoperfluorocarbons and persistent nitroxide radicals have been detected by ESR spectroscopy in solution. Quantitative data indicate that nitroxides behave as strong electron donors in halogen bonding, giving rise to interactions whose strength is close to that of strong hydrogen bonds. These results point to a novel design of supramolecular paramagnetic species.
Journal title
Tetrahedron Letters
Serial Year
2006
Journal title
Tetrahedron Letters
Record number
1849960
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