Title of article
Modulation of selectivity in a fluorocarbene cyclopropanation reaction: a catalytic role for bromide ion
Author/Authors
Moss، نويسنده , , Robert A. and Tian، نويسنده , , Jingzhi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2006
Pages
3
From page
3419
To page
3421
Abstract
Phenylfluorocarbene is diverted to phenylfluorobromomethide carbanion (PhCFBr−) by adding bromide ion. The carbanion adds to acrylonitrile leading, after expulsion of bromide, to 1-fluoro-1-phenyl-2-cyanocyclopropane.
Journal title
Tetrahedron Letters
Serial Year
2006
Journal title
Tetrahedron Letters
Record number
1850048
Link To Document