Title of article :
Modulation of selectivity in a fluorocarbene cyclopropanation reaction: a catalytic role for bromide ion
Author/Authors :
Moss، نويسنده , , Robert A. and Tian، نويسنده , , Jingzhi، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2006
Abstract :
Phenylfluorocarbene is diverted to phenylfluorobromomethide carbanion (PhCFBr−) by adding bromide ion. The carbanion adds to acrylonitrile leading, after expulsion of bromide, to 1-fluoro-1-phenyl-2-cyanocyclopropane.
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
