Title of article
Synthesis of diols using the hypervalent iodine(III) reagent, phenyliodine(III) bis(trifluoroacetate)
Author/Authors
Celik، نويسنده , , Murat and Alp، نويسنده , , Cemalettin and Co?kun، نويسنده , , Betül and Gültekin، نويسنده , , M. Serdar and Balci، نويسنده , , Metin، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2006
Pages
5
From page
3659
To page
3663
Abstract
1,2- and 1,3-Bis(trifluoroacetoxy) alcohols are easily obtained from the one-pot reaction of alkenes with phenyliodine(III) bis(trifluoroacetate) (PIFA) in the absence of any additive or catalyst. The products were converted into the corresponding diols by ammonolysis. The use of bicyclic alkenes has shown that rearranged 1,3-diacetoxy alcohols are mostly formed as the major products.
Keywords
Phenyliodine(III) bis(trifluoroacetate) , PIFA , Oxidation , Rearrangement , 1 , 1 , 2-diols , 3-Diols
Journal title
Tetrahedron Letters
Serial Year
2006
Journal title
Tetrahedron Letters
Record number
1850415
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