Title of article
Photochemical behaviors of tetraphenyldiphosphine in the presence of alkynes
Author/Authors
Kawaguchi، نويسنده , , Shin-ichi and Nagata، نويسنده , , Shoko and Shirai، نويسنده , , Takamune and Tsuchii، نويسنده , , Kaname and Nomoto، نويسنده , , Akihiro and Ogawa، نويسنده , , Akiya، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2006
Pages
4
From page
3919
To page
3922
Abstract
Under an atmosphere of nitrogen, the photoinduced reaction of tetraphenyldiphosphine (1) with alkynes (2) generates vicinal bisphosphinated alkenes (3) as air-sensitive compounds, which can be isolated by treatment with elemental sulfur. A novel E to Z isomerization of 3 is revealed to take place upon continuous photoirradiation.
Journal title
Tetrahedron Letters
Serial Year
2006
Journal title
Tetrahedron Letters
Record number
1850561
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