• Title of article

    Dicationic ((−)-sparteine)palladium-catalyzed enantioselective aldol reaction of aldehydes with 1-phenyl-1-trimethylsilyloxyethene, proceeding via a palladium enolate

  • Author/Authors

    Kiyooka، نويسنده , , Syun-ichi and Takeshita، نويسنده , , Yushi and Tanaka، نويسنده , , Yoshinori and Higaki، نويسنده , , Takafumi and Wada، نويسنده , , Yosuke، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2006
  • Pages
    4
  • From page
    4453
  • To page
    4456
  • Abstract
    A dicationic ((−)-sparteine)palladium complex underwent a superior catalytic enantioselective aldol reaction of aldehydes with 1-phenyl-1-trimethylsilyloxyethene performing satisfactorily, starting with ((−)-sparteine)PdCl2 and AgSbF6 as catalyst precursors (1 mol % loading) in the presence of 3 Å molecular sieves over the reaction.
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2006
  • Journal title
    Tetrahedron Letters
  • Record number

    1850848