Author/Authors :
Kim، نويسنده , , Sang Hee and Kim، نويسنده , , Hyung Gyu and Choo، نويسنده , , Hyunah and Cha، نويسنده , , Joo Hwan and Pae، نويسنده , , Ae Nim and Koh، نويسنده , , Hun Yeong and Chung، نويسنده , , Bong Young and Cho، نويسنده , , Yong Seo، نويسنده ,
Abstract :
N-Acyliminium ion cyclizations were studied with allenylmethylsilanes to synthesize nitrogen heterocycles. N-Acyliminium ion cyclizations were carried out by exposure of precursors 6 and 7 to Lewis acid. The precursors 6 were converted to pyrrolizidinone derivatives 9 with an exo-allene moiety, while the precursors 7 to indolizidinone derivatives 10 with an exo-1,3-diene moiety.