Author/Authors :
Grison، نويسنده , , Claude and Olszewski، نويسنده , , Tomasz K. and Crauste، نويسنده , , Céline and Fruchier، نويسنده , , Alain and Didierjean، نويسنده , , Claude and Coutrot، نويسنده , , Philippe، نويسنده ,
Abstract :
Unprecedented magnesium dihalide-catalysed Claisen rearrangement of 2-alkoxycarbonyl allyl vinyl ethers derived from α-chloroglycidic esters is reported in the glucidic series. A first application of this reaction concerns the stereoselective construction of a disaccharide analogue including a galactosyl and an ulosonic isopropyl ester moieties.
Keywords :
Claisen rearrangement , Magnesium dihalide , Ulosonic esters , Disaccharide analogues , ?-chloroglycidic esters
