Title of article :
Ionic-liquid-promoted Michaelis–Arbuzov rearrangement
Author/Authors :
Matveeva، نويسنده , , E.V. and Odinets، نويسنده , , I.L. and Kozlov، نويسنده , , V.A. and Shaplov، نويسنده , , A.S. and Mastryukova، نويسنده , , T.A.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2006
Abstract :
Room-temperature imidazolium ionic liquids, [Rmim][X], proved to be environmentally benign recyclable solvents promoting the Michaelis–Arbuzov rearrangement, which can be performed even at room temperature in a short period of time. The best ionic liquid of choice depended on the starting phosphorus(III) ester, namely, for triethyl phosphite [bmim][NTf2] demonstrated better results while for ethyl diphenylphosphinite it was [hmim][Br].
Keywords :
Ionic liquids , Michaelis–Arbuzov rearrangement , P–C bond formation
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
