Title of article
Ir-catalyzed asymmetric allylic amination using chiral diaminophosphine oxides
Author/Authors
Nemoto، نويسنده , , Tetsuhiro and Sakamoto، نويسنده , , Tatsurou and Matsumoto، نويسنده , , Takayoshi and Hamada، نويسنده , , Yasumasa، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2006
Pages
4
From page
8737
To page
8740
Abstract
An Ir-catalyzed asymmetric allylic amination using chiral diaminophosphine oxide is described. Asymmetric allylic amination of terminal allylic carbonates proceeded in the presence of 2 mol % of Ir catalyst, 2 mol % of chiral diaminophosphine oxide, 5 mol % of NaPF6, and BSA, affording the chiral branched allylic amines in up to 95% ee.
Keywords
Asymmetric catalysis , Asymmetric allylic amination , Diaminophosphine oxide , iridium
Journal title
Tetrahedron Letters
Serial Year
2006
Journal title
Tetrahedron Letters
Record number
1853477
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