Title of article :
1,5-Remote stereocontrol using allylgermanes
Author/Authors :
Castreno، نويسنده , , Pilar and Thomas، نويسنده , , Eric J. and Weston، نويسنده , , Anna P.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2007
Abstract :
Transmetallation of 5- and 4-alkoxypent-2-enylgermanes 8, 10 and 13 using tin(IV) chloride is stereoselective and generates allyltin trichlorides which react with aldehydes with useful levels of 1,5-stereocontrol.
Keywords :
Organogermanium , Remote stereocontrol , allylmetal , diastereoselectivity
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters