Author/Authors :
?y?wa، نويسنده , , Piotr and Jankowiak، نويسنده , , Aleksandra and Kwiatkowska، نويسنده , , Malgorzata G. Mikolajczyk، نويسنده , , Marian and Kie?basi?ski، نويسنده , , Piotr and Betz، نويسنده , , Alexander and Jaffres، نويسنده , , Paul-Alain and Gaumont، نويسنده , , Annie-Claude and Gulea، نويسنده , , Mihaela، نويسنده ,
Abstract :
A chiral racemic 2-phosphono-2,3-didehydrothiolane sulfoxide was used as a Michael acceptor in the reactions with several nucleophiles, in particular thiols. In most cases the reactions were fully diastereoselective. The relative configuration of the resulting adducts was determined.
Keywords :
Diastereoselective Michael additions , Phosphonothiolanes , ?-Sulfinylphosphonates , chiral sulfoxide
