• Title of article

    Nickel-catalyzed [4+3] cycloaddition of ethyl cyclopropylideneacetate and 1,3-dienes

  • Author/Authors

    Saito، نويسنده , , Shinichi and Takeuchi، نويسنده , , Kouhei، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2007
  • Pages
    4
  • From page
    595
  • To page
    598
  • Abstract
    The [4+3] cycloaddition of ethyl cyclopropylideneacetate (1) with 1,3-dienes proceeded in the presence of Ni(cod)2–TOPP (tri-o-biphenylyl phosphite). The reaction provided a new method for the synthesis of cycloheptene derivatives. The mechanism of the reaction was proposed.
  • Keywords
    Conjugated dienes , Methylenecyclopropane , cycloaddition , Cycloheptene
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2007
  • Journal title
    Tetrahedron Letters
  • Record number

    1854007