Author/Authors :
Bruno K. Bassora، نويسنده , , Bruno K. and Da Costa، نويسنده , , Carlos E. and Gariani، نويسنده , , Rogério A. and Comasseto، نويسنده , , Joمo V. and Dos Santos، نويسنده , , Alcindo A.، نويسنده ,
Abstract :
Reduction of (Z)-β-butyltelluro-enones gives the corresponding γ-hydroxy vinylic tellurides with retention of the double bond configuration. Reaction of γ-hydroxy vinylic tellurides with 2 equiv of n-butyllithium produces 1,4-C,O-dianions, which on reaction with carbon dioxide give the corresponding butenolides.