Author/Authors :
Pawluczyk، نويسنده , , Joseph M. and McClain، نويسنده , , Ray T. and Denicola، نويسنده , , Chris and Mulhearn Jr.، نويسنده , , James J. and Rudd، نويسنده , , Deanne Jackson and Lindsley، نويسنده , , Craig W.، نويسنده ,
Abstract :
Microwave heating of high-loading TEMPO-methyl resin with functionalized styrenyl monomers in an ADVANCER™ preparative scale microwave synthesizer affords larger resin beads (>375 μm) via living free radical polymerization (LFRP). Unlike homogeneous MAOS reactions, the heterogeneous LFRP reaction is not directly scalable and required significant optimization. Under modified conditions, high-loading Rasta resins (>3.8 mmol/g) are reproducibly obtained in 40–100 g quantities.
