Title of article
Microwave-initiated living free radical polymerization: optimization of the preparative scale synthesis of Rasta resins
Author/Authors
Pawluczyk، نويسنده , , Joseph M. and McClain، نويسنده , , Ray T. and Denicola، نويسنده , , Chris and Mulhearn Jr.، نويسنده , , James J. and Rudd، نويسنده , , Deanne Jackson and Lindsley، نويسنده , , Craig W.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
5
From page
1497
To page
1501
Abstract
Microwave heating of high-loading TEMPO-methyl resin with functionalized styrenyl monomers in an ADVANCER™ preparative scale microwave synthesizer affords larger resin beads (>375 μm) via living free radical polymerization (LFRP). Unlike homogeneous MAOS reactions, the heterogeneous LFRP reaction is not directly scalable and required significant optimization. Under modified conditions, high-loading Rasta resins (>3.8 mmol/g) are reproducibly obtained in 40–100 g quantities.
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1854313
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