Title of article :
Enzyme promiscuity: first protein-catalyzed Morita–Baylis–Hillman reaction
Author/Authors :
Reetz، نويسنده , , Manfred T. and Mondière، نويسنده , , Régis and Carballeira، نويسنده , , José Daniel، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2007
Abstract :
The Morita–Baylis–Hillman reaction of cyclohexenone and p-nitro benzaldehyde is catalyzed by carrier proteins such as serum albumins or enzymes such as certain lipases, conversion of up to 35% and enantioselectivities of up to 19% being observed.
Keywords :
enzymes and enzyme reactions , Enantioselection , Asymmetric reactions , Baylis–Hillman reactions , Proteins
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters