Title of article
Diastereoselective allylation of planar chiral substituted ferrocenecarboxaldehyde: an efficient entry to chiral ferrocenyl ligands
Author/Authors
Li، نويسنده , , Hao and Cheng، نويسنده , , Hin-Soon and Seow، نويسنده , , Ai-Hua and Loh، نويسنده , , Teck-Peng، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
3
From page
2209
To page
2211
Abstract
2,2′-Disubstituted ferrocenecarboxaldehydes are subjected to zinc-mediated allylation to form homoallylic ferrocenyl alcohols. The effects of ortho-substituted functional groups on facial selectivities of planar chiral aldehydes were studied and it was found that the corresponding homoallylic alcohols were obtained as single diastereomers in excellent yields.
Keywords
2?-Disubstituted ferrocenecarboxaldehydes , Chiral ferrocenyl complexes , allylation , 2
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1854555
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