Title of article :
Synthetic studies of spiroketal enol ethers: an unexpected oxidation by Martin’s sulfurane
Author/Authors :
Wensley، نويسنده , , Allison M. and Hardy، نويسنده , , Andrew O. and Gonsalves، نويسنده , , Kay M. and Koviach، نويسنده , , Jennifer L.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2007
Abstract :
In an attempt to synthesize a spiroketal enol ether natural product, we found that treatment of alcohol 5 with Martin’s sulfurane did not give the anticipated olefin, but instead afforded ketone 15 through an unprecedented oxidation.
Keywords :
Spiroketal enol ether natural products , Martin’s sulfurane , Propargylic oxidation , Sulfur-based oxidation
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
