Title of article :
Utility of a chiral 1,3-dioxane template in stereoselective intramolecular Diels–Alder reactions
Author/Authors :
Jego-Evanno، نويسنده , , Laurent and Deville، نويسنده , , Alexandre and Dubost، نويسنده , , Lionel and Chiaroni، نويسنده , , Angèle and Bodo، نويسنده , , Bernard and Nay، نويسنده , , Bastien، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2007
Abstract :
The ethylidene acetal of d-erythrose was used as a template for stereoselective IMDA reactions: high endo selectivity and yields in favor of the cis product were observed with 1,3,9-trienes, resulting from a boat transition state. For natural product synthesis, the reaction was successfully applied to a diene with terminal Z-olefin.
Keywords :
Diels–Alder reaction , Z-Diene , stereoselectivity , total synthesis , endo-Boat transition state
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
