Title of article
Domino pericyclic reactions of acyclic conjugated (E,Z,E,E)-tetraenes
Author/Authors
Skropeta، نويسنده , , Danielle and Rickards، نويسنده , , Rodney W.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
4
From page
3281
To page
3284
Abstract
Acyclic conjugated (E,Z,E,E)-tetraenes, upon thermolysis, undergo a domino pericyclic process involving 6π electrocyclisation of the (E,Z,E)-triene moiety to give the corresponding cis-disubstituted 5-vinyl-1,3-cyclohexadienes, followed by an intramolecular Diels–Alder reaction with the vinyl side chain to give tricyclo[3.2.1.02,7]oct-3-enes.
Keywords
Tetraenes , Electrocyclic reaction , Polyenes , intramolecular Diels–Alder reaction
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1854899
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