Author/Authors :
Kita، نويسنده , , Masaki and Roy، نويسنده , , Michael C. and Siwu، نويسنده , , Eric R.O. and Noma، نويسنده , , Isao and Takiguchi، نويسنده , , Takahiro and Yamada، نويسنده , , Kaoru and Koyama، نويسنده , , Tomoyuki and Iwashita، نويسنده , , Takeshi and Wakamiya، نويسنده , , Atsushi and Uemura، نويسنده , , Daisuke، نويسنده ,
Abstract :
Durinskiol A (1) is a long carbon-chain polyol compound with a molecular weight of 2128 mu isolated from the symbiotic dinoflagellate Durinskia sp. The relative stereochemistries of ether rings and sugar moieties in 1 were established based on 2D-NMR analysis and molecular modeling studies. Conformational analysis of the 6,5,6-bis-spiroacetal ring in 1 was also examined by using ab initio methods.
Keywords :
Configuration determination , Glycosides , molecular modeling , natural products , Super-carbon-chain compounds
