Author/Authors :
Fujita، نويسنده , , Takuma and Obata، نويسنده , , Kazuhiro and Kuwahara، نويسنده , , Shunsuke and Miura، نويسنده , , Nobuaki and Nakahashi، نويسنده , , Atsufumi and Monde، نويسنده , , Kenji and Decatur، نويسنده , , John and Harada، نويسنده , , Nobuyuki، نويسنده ,
Abstract :
Enantiopure (R)-(+)-[VCD(+)945]-4-ethyl-4-methyloctane, the simplest chiral saturated hydrocarbon with a quaternary stereogenic center, was synthesized by the use of MαNP acid method, and its absolute configuration was first unambiguously determined by the 1H NMR anisotropy, X-ray crystallography, and VCD methods.
Keywords :
Simplest chiral saturated hydrocarbon , vibrational circular dichroism , X-ray crystallography , 1H NMR anisotropy method
